happiness, luck
幸せ(しあわせ)、幸運(こううん)、不幸(ふこう)、幸い(さいわい)
happiness, good fortune, misfortune, fortunately
On-reading (コウ) is used in compounds; kun-reading (しあわ(せ)) is used standalone or with okurigana. Appears in many compounds — memorize the key ones rather than the kanji in isolation. This kanji forms verbs/adjectives with okurigana. Practice both the word form and compound forms.
From the JLP Quiz question bank — the word in the form it is actually tested in.
幸い、けが人はいませんでしたが、ビルの一部が焼けました。
Answer: 昨日の午後3時ごろ
家族や友達と一緒に行くことが多く、新しい年の健康や幸福を祈ります。
Answer: 新年に神社やお寺にお参りに行くこと